Can i use this to strap my sleeping mat to the rucksack ?

That is a possible although I don’t know if there is enough adjustment on the straps to give enough length. What I got them for was to stop the straps on a small backpack from slipping off the shoulders and they do that job fine. The straps are of course fitted across the chest.

I like to sling by backpack over one shoulder when walking, can these be attached in a way to stop it slipping off one shoulder?

You would need a longer strap which would go around your body

Some reviews say that these are wide for sternum straps. Would they work better as waist straps, if they're long enough?

I like them as sternum straps and find them comfortable I don’t find them too wide.

How do you attach please. I'm a novice hiker!

It goes round your backpack straps.

Backpack Chest Strap Adjustable Chest Strap Backpack Straps Sternum Strap

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Fully operational. Shipping worldwide, on schedule.Customs & duties included in the price

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Description

♥Fabric performance: Water/UV Resistant Polypropylene Webbing and durable.
♥Design features: 3/4-inch wide nylon webbing Dual with Ladder-Lock Side-Squeeze Buckles.
♥Easy to buckle and unbuckle: Each strap includes a slide lock so it can be quick release buckle.
♥Suit most backpack shoulder strap: Adjustable length from 4""-22"", compatible with most sizes.
♥Functional details: Keeps shoulder straps of your backpack securely in place, and gives your hands free.

Specifications:Color:Black.Size:Total length 27cm, adjusbale length from 15cm-22cm.Material:Made of 2cm wide polypropylene webbing, durable to use.Features:1.Keeps shoulder straps of your backpack securely in place, and gives your hands free.2.Easy to buckle and unbuckle,each strap includes a slide lock so it can be quick release buckle.3.Suit most backpack shoulder strap, adjustable length from 15cm-22cm, compatible with most sizes.Package includes:1 pcs backpack chest strap.

Specifications

ASIN	B07J4MVB78
Best Sellers Rank	449,726 in Fashion ( See Top 100 in Fashion ) 287 in Backpack Pack Straps
Customer reviews	4.2 4.2 out of 5 stars (655)
Date First Available	8 Oct. 2018
Department	Children's
Manufacturer	nuosen
Product Dimensions	27 x 2 x 0.1 cm; 40 g

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Backpack Chest Strap, Adjustable Chest Strap Backpack Straps Sternum Strap Chest Harness Chest Belt with Buckle for Kids Hiking and Jogging

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